Assessment of the relationship between magnetotransport and magnetocaloric properties in nano-sized La0.7Ca0.3Mn1-xNixO3 manganite
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Date
2018
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Institución Universitaria Pascual Bravo
Abstract
The effect of Ni2+substitution on the magneto-transport properties and the concomitant relationship with the magnetocaloric function of nano-sizedLa0.7Ca0.3Mn1−xNixO3(x = 0, 0.02, 0.07, and 0.10) perovskite manganites are reported. All the samples were synthesized using the auto-combustion method. X-raydiffraction analysis studies confirmed the phase purity of the synthesized samples. The substitution of Mn3+ions with Ni2+ions in the La0.7Ca0.3MnO3lattice wasalso verified using this technique. Rietveld analysis indicated that the volume of the unit cell increased with increasing Ni2+content. Zero-field-cooled andfield-cooled magnetization showed that all samples underwent a paramagnetic-ferromagnetic phase transition, which was concomitant with a metal-insulator transition.
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Gómez, Adrián & Chavarriaga, Edgar & Izquierdo, J.L. & Prado-Gonjal, Jesús & Mompean, F. & Rojas, Nestor & Morán, O.. (2018). Assessment of the relationship between magnetotransport and magnetocaloric properties in nano-sized La0.7Ca0.3Mn1-xNixO3 manganites. Journal of Magnetism and Magnetic Materials. 469. 10.1016/j.jmmm.2018.09.036.